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Kean, who was the victim of racist abuse during the week, came off the bench to score as Juventus came from behind to beat AC Milan 2-1.
Milan had been favoured to win the match after a run of five straight league victories but there was little evidence of the good play on display on Sunday.
Cristiano Ronaldo scored the only goal of the match to win his first trophy with the Italian team.
Gonzalo Higuain and Hakan Calhanoglu both missed chances for Milan.
Although Chelsea failed to keep a perfect group-stage record, Willian and Giroud salvaged a 2-2 draw against Vidi in Budapest by scoring from free kicks.
Sevilla, which has eclipsed Barcelona and Real Madrid so far this season to lead the way in the Spanish league, suffered a surprise 1-0 loss at Standard Liege in Group J.
It was Ronaldo's first goal in six matches at San Siro, having previously played at the iconic stadium for Manchester United and Real Madrid.
AC Milan suffered a shock 2-1 defeat against Real Betis at the San Siro, while Arsenal was unstoppable again as it remained perfect in the competition.
Inter star player Nainggolan hurt his ankle in a crunching tackle with Lucas Biglia in the first half. The Belgian midfielder will undergo tests on Monday but is now a doubt for Champions League match at Barcelona.
Arsenal, with former Sevilla coach Unai Emery now in charge, defeated Ukraine's Vorskla 4-2 thanks to a double from Pierre-Emerick Aubameyang and AC Milan edged past Dudelange of Luxembourg 1-0.
Juventus said in a statement that Bonucci and Caldara are direct swaps with each player being valued at 35 million euros ($41 million).
Wilkins had an illustrious career with Manchester United, Chelsea and AC Milan and had coached QPR and Fulham as well.
Marseille progressed after a 2-1 win at Athletic Bilbao that was marred by crowd trouble. Lazio advanced with a 2-0 win at Dinamo Kiev and Leipzig drew 1-1 at Zenit.
There was another surprise in Germany where two goals from Valon Berisha led Salzburg to a 2-1 victory at Borussia Dortmund.
Juventus was also slated to host Atalanta in Serie A on Sunday but that match was snowed out and will be made up March 14.
Athletic Bilbao are scheduled to next face Marseille, while Borussia Dortmund will take on Austrian side Salzburg.
Shockingly, Serie A leaders Napoli weren't good enough to advance in the Europa League on Thursday after they were knocked out in Germany by RP Leipzig.
In other ties, Scottish club Celtic F.C will host Russian club Zenit St Petersburg, Napoli will play RB Leipzig, Ludogorets will take on seven-time European champions AC Milan.
Unable to produce inspiring results with a completely revamped squad, Montella was fired as coach of AC Milan and replaced by Gennaro Gattuso.
Lyon routed Apollon 4-0 and Atalanta hammered Everton 5-1 in Goodison Park, leaving the Premier League side winless, to confirm their dominance in Group E.
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