64-year-old Munde, who made his entry into the Union Cabinet for the first time last week, was on his way to the airport when his car was hit by another vehicle at Prithviraj Road-Tughlak Road intersection in the heart of the capital.
Various political leaders have demanded a CBI probe to ascertain the reasons behind his death.
Republican Party of India Chief Ramdas Athawale has demanded CBI inquiry into the death of the Union Minister.
