"The injured was admitted to Durg hospital," the DGP said, adding, the body of the deceased has been brought to Raipur for postmortem.
A magisterial inquiry has been ordered into the incident and the CRPF man has been removed from duty, he said.
A total of 843 candidates are contesting with an electorate of 1,39,75,470 in the last of the two-phase polls to the 90-member Assembly in the state where BJP government, led by Chief Minister Raman Singh, is eyeing for a hat-trick against the Congress.
Live reporting: Chhattisgarh records around 75 percent polling in 2nd phase
Raipur: Nearly 75 per cent voters in 72 constituencies across 19 districts of Chhattisgarh exercised their franchise till 5 PM today in the second and last phase of Assembly polls even as a man was
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